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If sodium acetate is added to a solution of acetic acid, Le Châtelier’s principle predicts that the equilibrium in Equation 16.54 will shift to the left, consuming some of the added CH 3 CO 2 − and some of the H + ions originally present in solution: Because Na + is a spectator ion, it has no effect on the position of the equilibrium and can be ignored

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10.1021/ja01315a102