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87,88 Nanomaterials are used as a conductive bridge for oxidation/reduction as enzymatic biocatalyst with heme-c containing PQQ 90 S-PQQ/GDH from Acinetobacter calcoaceticus when covalently attached to electro-polymerized polyaniline co-polymer film on MWCNT mediated gold electrode showed efficient bio-electro catalytic conversion of glucose for biofuel cell (Figure 19).Involving both the direct and mediated electron transfer (DET and MET) the mechanisms for which involve (MWCNTs) with different immobilization techniques